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Solar Power in Building Design
Author: Peter Gevorkian, Ph.D., P.E.,
ASIN: B00121SIIM
Publisher: McGraw-Hill Professional

Solar Cell Physics

Most solar cells are constructed from semiconductor material, such as silicon (the fourteenth element in the Mendeleyev table of elements). Silicon is a semiconductor that has the combined properties of a conductor and an insulator.

Metals such as gold, copper, and iron are conductors; they have loosely bound electrons in the outer shell or orbit of their atomic configuration. These electrons can be detached when subjected to an electric voltage or current. On the contrary, atoms of insulators, such as glass, have very strongly bonded electrons in the atomic configuration and do not allow the flow of electrons even under the severest application of voltage or current. Semiconductor materials, on the other hand, bind electrons midway between that of metals and insulators.

Semiconductor elements used in electronics are constructed by fusing two adjacently doped silicon wafer elements. Doping implies impregnation of silicon by positive and negative agents, such as phosphor and boron. Phosphor creates a free electron that produces so-called N-type material. Boron creates a “hole,” or a shortage of an electron, which produces so-called P-type material. Impregnation is accomplished by depositing the previously referenced dopants on the surface of silicon using a certain heating or chemical process. The N-type material has a propensity to lose electrons and gain holes, so it acquires a positive charge. The P-type material has a propensity to lose holes and gain electrons, so it acquires a negative charge.

When N-type and P-type doped silicon wafers are fused together, they form a PN junction. The negative charge on P-type material prevents electrons from crossing the junction, and the positive charge on the N-type material prevents holes from crossing the junction. A space created by the P and N, or PN, wafers creates a potential barrier across the junction.

This PN junction, which forms the basic block of most electronic components, such as diodes and transistors, has the following specific operational uses when applied in electronics:

In diodes, a PN device allows for the flow of electrons and, therefore, current in one direction. For example, a battery, with direct current, connected across a diode allows the flow of current from positive to negative leads. When an alternating sinusoidal current is connected across the device, only the positive portion of the waveform is allowed to pass through. The negative portion of the waveform is blocked.

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